Cukurova University,Department of Textile Engineering, Main Branch of Textile Technology

Showing posts with label Polydopamine. Show all posts
Showing posts with label Polydopamine. Show all posts

November 17, 2024

Investigation of the oxidative selfpolymerization of dopamine under alkaline conditions on wool fabrics


Most studies about polydopamine in the textile field have been related to cotton fibers. There are not many studies about the use of polydopamine on wool fibers. A limited number of studies have focused on the coloring of wool, whereas wool is the fiber with the highest variety of intermolecular attraction forces among all natural and man-made fibers. 

Polydopamine contains high amounts of catechol and amine functional groups due to its structure. In this study, different from the literature, oxidative self polymerization of dopamine was achieved on wool fabric for different periods of time, and the coated fabrics were examined with characterization tests and spectrophotometrically. 

In this study, lower values were obtained than lightness (L*) values reported for other fibers in previous studies, and it was concluded that the wool-PDA interaction is superior to other fibers. Scanning electron microscopy and energy dispersive X-ray spectroscopy results showed that the polymerization and nano-coating formed successfully and continued to remain on the surface after washing. 

The lowest lightness value was obtained in the 32 h coating. However, the lowest color change after washing was in the 16 h coating (0.44%). This result showed that the coating was completed within 16–32 hours and there was only accumulation on the surface in the later times.


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March 28, 2022

The use of mussel‑inspired polydopamine interlayer for high‑efficiency surface functionalization of PET fabrics


The surface modifications of polymer materials are carried out to improve surface properties, add new functionalities and thus enlarge their application areas. Polyethylene terephthalate (PET) is a commonly used textile fabric to achieve functional properties via surface modification techniques. However, its inert and non-reactive nature necessitates an activation process before the surface modification to create functional surfaces. Plasma treatment and chemical methods are commonly used for this aim. However, these techniques can easily damage the surface of the PET fabric and result in decreased mechanical properties. In this study, we proposed a new method to activate the surface of PET using polydopamine (PDA) interlayer, known as substrate-independent coating material, to form a better and more homogenous polyaniline (PAni) coating via an in-situ polymerization technique. The surface appearance of the samples was investigated using scanning electron microscopy, and the distribution of elements was analyzed using an energy-dispersive (EDS) detector. Thermal properties of the samples were explored using thermogravimetric analyses and Fourier-transform infrared spectroscopy was used to compare the chemical structures of the coated and uncoated samples. It was found that the PDA interlayer between PAni and PET significantly reduced the sheet resistance by providing more homogenous and chemically stable PAni coatings. Moreover, the effect of the PDA and PAni coating on the optical properties was investigated, and it was found that the PDA + PAni coated fabric exhibited a maximum of 10% reflectance in the range of 400 and 700 nm while uncoated fabric showed over 90%.

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